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Metalloporphyrinic metal–organic frameworks for enhanced photocatalytic degradation of a mustard gas simulant

https://doi.org/10.1039/D4CC03890H

Quon, Alisa S; Manriquez, Doroteo; Nguyen, Anna; Papazyan, Edgar K; Wijeratne, Pavithra; An, Lun; Qi, Long; Tang, Matthew J; Ready, Austin D; Farha, Omar K; et al (October 2024, Chemical Communications)

Four metalloporphyrinic metal–organic frameworks (MOFs) were successfully synthesized and exhibited enhanced activities for the photooxidation of a sulfur mustard simulant, 2-chloroethyl ethyl sulfide (CEES). Among them, a Sn-porphyrin functionalized 2D MOF, namely CSLA-21-NH2(Sn), showed a half-life of 1.5 min for CEES oxidation under blue LED, featuring as one of the fastest photocatalysts for CEES degradation.
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Redox-Active Boron Clusters

https://doi.org/10.1021/acs.accounts.4c00040

Ready, Austin D; Nelson, Yessica A; Torres_Pomares, Daniel F; Spokoyny, Alexander M (May 2024, Accounts of Chemical Research)

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Electrochemical Cycling of Redox-Active Boron Cluster-Based Materials in the Solid State

https://doi.org/10.1021/jacs.3c03065

Ready, Austin D.; Irshad, Ahamed; Kallistova, Anna; Carrillo, Moises; Gembicky, Milan; Seshadri, Ram; Narayan, Sri; Spokoyny, Alexander M. (July 2023, Journal of the American Chemical Society)

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Sterically Invariant Carborane-Based Ligands for the Morphological and Electronic Control of Metal–Organic Chalcogenolate Assemblies

https://doi.org/10.1021/acs.chemmater.2c01319

Mills, Harrison A.; Jones, Christopher G.; Anderson, Kierstyn P.; Ready, Austin D.; Djurovich, Peter I.; Khan, Saeed I.; Hohman, J. Nathan; Nelson, Hosea M.; Spokoyny, Alexander M. (August 2022, Chemistry of Materials)

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Benchmarking the dynamic luminescence properties and UV stability of B ₁₈ H ₂₂ -based materials

https://doi.org/10.1039/d2dt01225a

Anderson, Kierstyn P.; Hua, Ash Sueh; Plumley, John B.; Ready, Austin D.; Rheingold, Arnold L.; Peng, Thomas L.; Djurovich, Peter I.; Kerestes, Christopher; Snyder, Neil A.; Andrews, Andrew; et al (June 2022, Dalton Transactions)

The dynamic photoluminescence properties, and potential quenching mechanisms, ofanti-B₁₈H₂₂, 4,4′-Br₂-anti-B₁₈H₂₀, and 4,4′-I₂-anti-B₁₈H₂₀are investigated in solution and polymer films.
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